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Spin-Hamiltonian parameters and tetragonal distortion due to the Jahn–Teller effect for Cu2+ centres in trigonal Zn(BrO3)·6H2O crystal

✍ Scribed by Feng, Wen-Lin; He, Lv; Yang, Wei-Qing; Zheng, Wen-Chen


Book ID
111944664
Publisher
Taylor and Francis Group
Year
2009
Tongue
English
Weight
125 KB
Volume
107
Category
Article
ISSN
0026-8976

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Investigations of the spin-Hamiltonian p
✍ Yang Mei; Wen-Chen Zheng 📂 Article 📅 2009 🏛 Elsevier Science 🌐 English ⚖ 137 KB

The complete high-order perturbation formulas based on a two-mechanism [i.e., crystal-field (CF) and charge-transfer (CT) mechanisms, the latter is neglected in the widely-used CF theory] model for the spin-Hamiltonian (SH) parameters (g factors g // , g ? and the hyperfine structure constants A //