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Spin Dimer Analysis for Antiferromagnetic Spin Exchange Interactions of Magnetic Solids with Several Unpaired Electrons per Spin Site: Trends in the Spin Exchange Parameters of the Compounds Consisting of MnF5 Chains and CrX2 (X=O, S) Layers

✍ Scribed by H.-J. Koo; M.-H. Whangbo; S. Coste; S. Jobic


Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
182 KB
Volume
156
Category
Article
ISSN
0022-4596

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✦ Synopsis


For magnetic solids with several unpaired spins per spin site, the average spin orbital interaction energies 1 e2 and the average spin orbital interaction energy squares 1( e) 2 2 were de5ned as a qualitative measure for the strengths of their antiferromagnetic spin exchange interactions. The trends in the antiferromagnetic spin exchange interactions of the magnetic solids containing MnF 5 chains and CrX 2 (X ‫؍‬ O, S) layers were examined in terms of the 1 e2 and 1( e) 2 2 values calculated for their spin dimers.