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Spin density in a nitronyl nitroxide free radical. Polarized neutron diffraction investigation and ab initio calculations

✍ Scribed by Zheludev, Andrei; Barone, Vincenzo; Bonnet, Michel; Delley, Bernard; Grand, Andre; Ressouche, Eric; Rey, Paul; Subra, Robert; Schweizer, Jacques


Book ID
120987770
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
1013 KB
Volume
116
Category
Article
ISSN
0002-7863

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The spin density in an imino nitroxide f
✍ A. Zheludev; M. Bonnet; D. Luneau; E. Ressouche; P. Rey; J. Schweizer πŸ“‚ Article πŸ“… 1995 πŸ› Elsevier Science 🌐 English βš– 263 KB

Imino nitroxide free radicals are potential building blocks for molecular-based magnets. They are purely organic and carry a spin Β½ which is delocalized over several atoms of the molecule. We have determined the spin density of one of them, the 2-(3-nitrophenyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-im