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Spin density distributions in some fluorinated radical anions

✍ Scribed by N.K. Ray

Publisher
Elsevier Science
Year
1969
Tongue
English
Weight
244 KB
Volume
3
Category
Article
ISSN
0009-2614

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✦ Synopsis

A one-parameter relation between isotropic fluorine splitting and %electron spin density on attached carbon is shown to be adequate to explain the fluorine splittings in various fluorinated radical anions.

πŸ“œ SIMILAR VOLUMES

Spin density distributions in some fluor
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## Abstract A theoretical study of π‐electron spin density distributions has been made for a series of fluoro‐substituted hydrocarbon radical cations using unrestricted Hartree‐Fock theory. Although some of the predicted proton splittings are not in very good agreement with experiment, the overall

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The isotropic and anisotropic ESR spectra of dialkyl oxalate radical anions, including derivatives which were labelled with "C or "0 in the carbonyl and \*H or "C in the alkyl groups, were measured. The spin density distribution as determined from the experimental nuclear hyperfine coupling constant