Spin density distributions and conformational properties of some thiophen radicals
β Scribed by A. Hudson; J.W.E. Lewis
- Book ID
- 108374058
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- French
- Weight
- 405 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0040-4020
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π SIMILAR VOLUMES
## Spin density distributions in ethyl, isopropyl and t-butyl radicals have been obtained by employing the unrestricted Hartree-Fock procedures and using hyperconjugative and hyperconjugative-inductive models for the methyl group. The results are in quite good agreement with experiment.
## Abstract ESR. spectra of the chlorine substituted phenoxy radicals listed in Table 1, which were produced by photoβoxidation of the parent phenols in aprotic solvents, are reported. In most cases the chlorine splittings could be resolved and analysed in detail. Experimental data as well as quant