Spin delocalization from paramagnetic metal complexes [Cr(acac)3 and Fe(acac)3] to saturated hydrocarbons in CHCl3 and CCl4 solutions

✍ Scribed by Alexander N. Kitaigorodskii; Alexander G. Stepanov; Vyatcheslav M. Nekipelov

• Book ID: 102951241
• Publisher: John Wiley and Sons
• Year: 1986
• Tongue: English
• Weight: 569 KB
• Volume: 24
• Category: Article
• ISSN: 0749-1581
• DOI: 10.1002/mrc.1260240815

✦ Synopsis

Paramagnetic =C NMR shifts induced by tris(acetylacetonato)chromium(III) [Cr(acac),] and tris(acety1acetonato)iron(III) [Fe(acac)J in various saturated hydrocarbons were determined for the first time using a special technique.

The observed shifts, hasw, are the result of partial delocalization of unpaired electrons from the paramagnetic complexes on the alkanes. The value of depends strongly on the position of a carbon atom in the hydrocarbon molecule, and tends to decrease on passing from primary to quaternary carbon atoms. The observed spin transfer seems to reflect the 'contact charge transfer.' The A6,,, shifts in the unsaturated hex-1-ene only slightly exceed those in alkanes.

KEY WORDS Paramagnetic 13C NMR shifts Cr(acac), Fe(acac), saturated hydrocarbons hex-1-ene contact charge transfer