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Spin crossover studies in tris(N,N′-dialkyldithiocarbamato)iron(III) complexes

✍ Scribed by Sonal Singhal; A. N. Garg; Kailash Chandra

Book ID: 106546816
Publisher: Springer
Year: 2005
Tongue: English
Weight: 457 KB
Volume: 30
Category: Article
ISSN: 0340-4285
DOI: 10.1007/s11243-004-2256-3

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## Abstract Thermal spin crossover (SCO) was induced in a high‐spin Fe^III^ complex by alkylation of the polyamino ligand backbone. The SCO profile was responsive to chain length with partial crossover observed with C~6~ alkylation and full transition upon lengthening to C~12~. No crossover was obs