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Spin and charge transfer through hydrogen bonding in [Co(NH3)5(OH2)][Cr(CN)6]

✍ Scribed by Figgis, Brian N.; Kucharski, Edward S.; Vrtis, Mary


Book ID
127377651
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
749 KB
Volume
115
Category
Article
ISSN
0002-7863

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The coexistence of di4erent valences of iron and cobalt in cobalt pentacyanoferrate, CoFe(CN) 5 NH 3 ' 6H 2 O, was con-5rmed by the infrared spectrum, in which two distinct peaks for the C+N stretch at 2162 cm ؊ 1 and 2117 cm ؊ 1 were assigned to CN in Fe III +CN+Co II and Fe II +CN+Co III respectiv