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Sphingolipids as Coenzymes in Anion Transfer and Tumor Death

✍ Scribed by Norman S. Radin


Book ID
101963837
Publisher
John Wiley and Sons
Year
2005
Weight
8 KB
Volume
36
Category
Article
ISSN
0931-7597

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Ξ±-Silyl Ethers as Hydroxymethyl Anion Eq
✍ Guido Gutenberger; Eberhard Steckhan; Siegfried Blechert πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 113 KB πŸ‘ 1 views

Nucleophilic Ξ±-hydroxymethyl radicals can be generated from Ξ±-silyl ethers by irradiation in the presence of 9,10-anthracenedicarbonitrile (ADC) and biphenyl (BP). Under these conditions the hydroxymethyl radicals are not oxidized further but add directly to electron-poor alkenes [Eq. (a); EWG=elect