Since aromaticity [1] is not confined only to planar rings but also exists in three-dimensional systems, [2] the same should be true of homoaromaticity. [3±5] Although the 4Nþ2 H¸ckel electron-counting rule is defined for planar systems it has been applied to rationalize the properties of three-dime
✦ LIBER ✦
Spherical Homoaromaticity
✍ Scribed by Zhongfang Chen; Haijun Jiao; Andreas Hirsch; Paul von Ragué Schleyer
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 158 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0044-8249
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## Abstract A MINDO/3 study of homoaromaticity in the 3‐cyclobutenyl cation and the Mobius 3‐cyclobutenyl anion has been used to evaluate cationic and anionic homoaromaticity quantitatively. π Homodelocalization energies of the two are found equal in isostructural planar comparisons. In planar opti