✦ LIBER ✦
Spectroscopy of Σ00→Π10 Vibrational–Tunneling–Rotational Band in Rg · ND3 (Rg = Ne, Ar, Kr)
✍ Scribed by Dmitry G. Melnik; Terry A. Miller; Frank C. De Lucia
- Publisher
- Elsevier Science
- Year
- 2002
- Tongue
- English
- Weight
- 241 KB
- Volume
- 214
- Category
- Article
- ISSN
- 0022-2852
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✦ Synopsis
A number of vibrational-tunneling-rotational (VTR) transitions in the range of 195-298 GHz belonging to the 0 0 → 1 0 hindered rotation band in Rg • ND 3 (Rg = Ne, Kr) complexes are observed in absorption in a free supersonic jet, using the pulsed fast scan submillimeter-wave spectroscopic technique (FASSST). The data obtained in this experiment, combined with previously obtained data on the Ar • ND 3 complex, were used to construct a qualitative model describing the inversion-tunneling motion in the lowest states of the Rg • ND 3 complexes.