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Spectroscopy of Hexafluorides with an Odd Number of Electrons: Operators of Interest for Electronic Spectroscopy and for the Jahn-Teller Effect

✍ Scribed by V. Boudon; F. Michelot; J. Moretbailly

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
821 KB
Volume
166
Category
Article
ISSN
0022-2852

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✦ Synopsis

A simplified model describing the electronic levels of a (\left(f_{28}\right)^{n}) configuration is proposed. A new tensorial formulation for Jahn-Teller (linear, quadratic, . . .) operators is developed. Particular attention is given to the case of electronic states with (G^{\prime}) symmetry and to their vibronic structures. Calculations and predictions are made for the (a) and (e) electronic states of (\operatorname{lrF}_{6}). ic 1994 Academic Press. Inc.

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