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Spectroscopy and ultrafast dynamics of the 2A1 state of Z-hexatriene in gas phase

✍ Scribed by Fu\S, W.; Schikarski, T.; Schmid, W. E.; Trushin, S. A.; Hering, P.; Kompa, K. L.

Book ID
120047933
Publisher
American Institute of Physics
Year
1997
Tongue
English
Weight
446 KB
Volume
106
Category
Article
ISSN
0021-9606

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✍ Hopf, Henning ;Wachholz, Gerhard ;Walsh, Robin πŸ“‚ Article πŸ“… 1992 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 931 KB

4‐Methyl‐1,2,5‐hexatriene (13) has been prepared and subjected to gas‐phase pyrolysis. Above 220Β°C, 13 rearranges reversibly to both __trans__‐5‐hepten‐1‐yne (14) and its __cis__‐isomer 15. Formation of 14 is faster than that of 15. These isomerisations are accompanied by a slower irreversible rearr