The rate constant for the self-reaction of the peroxyl radical derived from methanol, HOCH,OO', has been measured over the temperature range 5-53Β°C. The radical has a maximum absorptivity of 970 I! mol-' cm-' at 240 nm and an absorptivity of about 510 P mol-' cm-' at 280 nm. From a modified Arrheniu
Spectroscopy and reaction kinetics of HS radicals
β Scribed by J.J. Tiee; F.B. Wampler; R.C. Oldenborg; W.W. Rice
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 423 KB
- Volume
- 82
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
A laser-mduced fluorescence
technique is used to monitor the HS radical concentration.
The rate constants at room temperature have been determined for the reaction of HS radical with various added scavengers.
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