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Spectroscopy and Quantum Chemical Modeling Reveal a Predominant Contribution of Excitonic Interactions to the Bathochromic Shift in α-Crustacyanin, the Blue Carotenoprotein in the Carapace of the Lobster Homarus gammarus

✍ Scribed by van Wijk, Arjan A. C.; Spaans, Arnold; Uzunbajakava, Natallia; Otto, Cees; de Groot, Huub J. M.; Lugtenburg, Johan; Buda, Francesco

Book ID
121485462
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
162 KB
Volume
127
Category
Article
ISSN
0002-7863

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Resonance Raman spectroscopy and quantum
Resonance Raman spectroscopy and quantum chemical modeling studies of protein–astaxanthin interactions in α-crustacyanin (major blue carotenoprotein complex in carapace of lobster, Homarus gammarus)
✍ R. J. Weesie; J. C. Merlin; H. J. M. De Groot; G. Britton; J. Lugtenburg; F. J. 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 288 KB 👁 2 views

Resonance Raman spectroscopy and quantum chemical calculations were used to investigate the molecular origin of the large redshift assumed by the electronic absorption spectrum of astaxanthin in alpha-crustacyanin, the major blue carotenoprotein from the carapace of the lobster, Homarus gammarus. Re