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Spectroscopy and kinetics of the 1P1 and 3P2 states of Hg 6s6p in xenon

โœ Scribed by Anthony B. Callear; Kangyan Du

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
1018 KB
Volume
113
Category
Article
ISSN
0301-0104

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๐Ÿ“œ SIMILAR VOLUMES

Kinetic processes of Hg6s6p(3P1) in xeno
Kinetic processes of Hg6s6p(3P1) in xenon
โœ Anthony B. Callear; Kangyan Du ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 411 KB

The principal route for decay of Hg 6s6~(~P,) in xenon is shown to be bimolecular deactivation to the mercury ground state, with rate coefficient 9.1 x lo-l3 cm3 molecule-' s-l. , relaxation to the 3Po state plays a negligible role. The equilibrium constant of the reaction Hg(3P,) + Xe # HgXe(A 30')

Temperature dependence of the Hg 6s6p(3P
Temperature dependence of the Hg 6s6p(3P0โ†’3P1) transition induced by nitrogen
โœ Anthony B. Callear; Paul M. Shiundu ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 331 KB

The rate coefficient of the process Hg 6s6p( 'P 0-+3P, ) induced by nitrogen collisions has been measured over the range 285 to 340 K. The temperature variation closely matches that of the concentration of Nz( u= 1). The results support the electronic to vibrational energy-transfer mechanism for the