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Spectroscopy and dynamics of jet-cooled 1,1′ binaphthyl

✍ Scribed by Harry T. Jonkman; Douwe A. Wiersma

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
343 KB
Volume
97
Category
Article
ISSN
0009-2614

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✦ Synopsis

Fluorescence escitation and dispcrscd lluorcscencc spectra of jet-cooled 1 .I'-binaphthyl are reported and sndlysed. The spectra indicate that in the ground Jnd exited state the naphthalene rings are pcrpendiculdr to one another. The spectrs cdn be Iitrthrr interpreted in terms of an ehciton model with an cxciton splittin_r of 21 cm-' . m tile origin. From the structurelcss emission spectrum and lifetime ir. is concluded lhl, in the isolated molecule, efficient vibrational relaation

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