The absorption and emission spectra, emission lifetimes, luminescence quantum yields, and electrochemical behavior of the complexes Pd(Phpy),, Pd(Thpy),, and Pd(bhq), (Phpy-, Thpy-, and bhq-are the deprotonated forms of 2-phenylpyridine, 2-(2-thienylfpyridine, and benzo[h]quinoline, respectively) ha
Spectroscopical and Electrochemical Behavior of New Mixed-Ligand Cyclometalated Rh(III) Complexes
β Scribed by Diana Sandrini; Mauro Maestri; Mauro Ciano; Urs Maeder; Alex von Zelewsky
- Publisher
- John Wiley and Sons
- Year
- 1990
- Tongue
- German
- Weight
- 454 KB
- Volume
- 73
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Two series of cyclometallated and noncyclometallated observed for the two series: a remarkable feature is the observation of relatively long-lived MLCT excited states ruthenium(II) complexes incorporating mono-or disubstituted 1,10-phenanthroline-and 2,2Π:6Π,2ΠΠ-terpyridine-type (from 70 to 106 ns a
## Abstract A series of cationic diiminoiridium(III) complexes [Ir(ppyβ__N__,__C__)~2~(Lβ__N__,__N__)](PF~6~) has been prepared [Hppy = 2βphenylpyridine; L = 4,4β²β__t__Bu~2~dpbpy (1), 4,4β²βMe~2~dpbpy (2), 4,4β²βMe~2~pbpy (3), 4,4β²βMe~2~bpy (4)] and their photophysical and electrochemical properties
The paramagnetic complexes ( FPc )( Me ) Rh ^-^ (4) and (FPc)( PMe ~3~)( Me ) Rh ^-^ (10) have been prepared by reducing ( FPc )( Me ) Rh (1) and ( FPc )( PMe ~3~)( Me ) Rh (2) with NaBH ~4~ in methanol-d~4~ [ FPc ^2-^ = dianion of 1,4,8,11,15,18,22,25-octakis(trifluoromethyl)phthalocyanine]. Compou