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Spectroscopic study of the structure of N-(2-benzimidazolyl)-O-methylcarbamate

โœ Scribed by B. E. Zaitsev; M. V. Palishkin; S. S. Kukalenko; V. P. Brysova


Book ID
112356156
Publisher
Springer US
Year
1986
Tongue
English
Weight
549 KB
Volume
22
Category
Article
ISSN
0009-3122

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The reaction mechanisms of the alkaline hydrolysis of N-methylcarbamates were studied using the AM1 method by assuming two possible pathways: (1) nucleophilic attack of hydroxide ion on the car-bony1 carbon to give a tetrahedral complex followed by its breakdown to carbamic acid (BA,~); and (2) prot