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Spectroscopic studies of the ν2 mode of methyl iodide by Raman spectroscopy

✍ Scribed by F.G. Baglin; H. Versmold

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
165 KB
Volume
96
Category
Article
ISSN
0009-2614

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✦ Synopsis

I'oLmzcd Ram.m studies of rhe ~3~ mode in methyl iodide at 1 and 1600 bar have confmed, through an independent r~wte. the rest&\ prex iousl~ found b> isolopic-dilution studies. By using a cubic-closepacked approximation of the liquid state 2nd _I I/r0 mlvrxt~on pofcnti.ti for dipolar dcpbasin, '7 between molecules. the data may be reconciled. This result is interrrcrcd IIT br sIwns e\idmcc for rbr dominance of the intermolecular transition-dipole dephssing mechanism.

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