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Spectroscopic studies of side-on and end-on bonding of dinitrogen in low-valent binuclear titanium amide complexes

✍ Scribed by Beatrix Goerdt; Robbert Duchateau; Sandro Gambarotta; Felix Tuczek


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
73 KB
Volume
59
Category
Article
ISSN
0162-0134

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Lewis Adducts of the Side-On End-On Dini
✍ Felix Studt; Bruce A. MacKay; Samuel A. Johnson; Brian O. Patrick; Michael D. Fr 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 334 KB 👁 1 views

## Abstract Reaction of the side‐on end‐on dinitrogen complex [{(NPN)Ta}~2~(μ‐H)~2~(μ‐η^1^:η^2^‐N~2~)] (1; in which NPN=(PhNSiMe~2~CH~2~)~2~PPh), with the Lewis acids XR~3~ results in the adducts [{(NPN)Ta}~2~(μ‐H)~2~(μ‐η^1^:η^2^‐NNXR~3~)], XR~3~=GaMe~3~ (2), AlMe~3~ (3), and B(C~6~F~5~)~3~ (4). Th