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Spectroscopic Properties of Al 2 P 2 , Al 2 P 2+ , and Al 2 P 2- and Comparison with Their Ga and In Analogues

✍ Scribed by Feng, Ping Yi; Balasubramanian, K.


Book ID
127147136
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
64 KB
Volume
103
Category
Article
ISSN
1089-5639

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EPR spectra of Al[P(CH3)3]2 and Al[P(OCH
✍ M. Histed; J.A. Howard; H.A. Joly; B. Mile πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 English βš– 362 KB

EPR examination of the products of the reaction between Al atoms and P(CHs)s and P(OCHs)s on a rotating cryostat in hydrocarbon matrices at 77 K reveals the presence of the seven-electron binary complexes A1[P(CH&12 and Al[P(OCHX)3]2. The magnetic parameters of these complexes are consistent with b