Spectroscopic parameters of nucleophilic and electrophilic reactivity

✍ Scribed by R.E. Ballard; Jimmy Jones; Elizabeth Sutherland

• Book ID: 104221923
• Publisher: Elsevier Science
• Year: 1982
• Tongue: French
• Weight: 227 KB
• Volume: 23
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)88655-4

✦ Synopsis

Reactions of a distinct charge transfer nature (exampled by those between N,N-dimethylaniline and N-methyl cations) are associated with charge transfer bands, in the visible, of energy hv = I -E + C where I is the ionisation energy of the nucleophile, E is the electron affinity of the electrophile and C is a correction term. As an example, the reaction between N,N-dimethylaniline and N-methylacridinium chloride is examined in detail.