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Spectroscopic Observation of Ion-Induced Water Dimer Dissociation in the X-·(H2O)2 (X = F, Cl, Br, I) Clusters

✍ Scribed by Ayotte, Patrick; Nielsen, Steen B.; Weddle, Gary H.; Johnson, Mark A.; Xantheas, Sotiris S.

Book ID
111649823
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
132 KB
Volume
103
Category
Article
ISSN
1089-5639

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Bond strengths of the gas-phase cluster
Bond strengths of the gas-phase cluster ions X− (CS2)n (X = F, Cl, Br and I)
✍ Kenzo Hiraoka; Susumu Fujimaki; Kazuo Aruga; Shinichi Yamabe 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 467 KB

Thermodynamic quantities, AH:\_ ,,\* and AS:\_ ,,", for the clustering reactions, X-(CSI),\_,+CSz=X-(CS,),, X=F, Cl, Br and I, were measured with a pulsed electron-beam high-pressure mass spectrometer. A large binding energy, 35.0 kcal/mol, for F-...CS2 has been obtained, whereas those for other X-.