The crystalline-state photopolymerization reaction mechanism in the dimethyl ester of p-phenylenediacrylic acid (p-PDAMe) was investigated. Raman phonon spectroscopic studies revealed that the reaction proceeds by a heterogeneous mechanism as the reactant and the product do not form a solid solution
✦ LIBER ✦
Spectroscopic manifestations of charge separation in the organic solid state: a UPS study of zwitterionic glycine
✍ Scribed by R.W. Bigelow; W.R. Salaneck
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 469 KB
- Volume
- 89
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Results of vapor-and condensed-phase UPS measurements and CNDO/S computations are used to address the modifications to the ordering of glycine orbitals due to charge separation upon conversion from the tree molecule to the zwitterionic solid-state conformation.
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