✦ LIBER ✦

Spectroscopic, magnetic and thermogravimetric studies of piperazine-bis-(dithiocarbamate) complexes

✍ Scribed by Antonio Costantino Fabretti; Fabrizia Forghieri; Aleardo Giusti; Carlo Preti; Giuseppe Tosi

Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 315 KB
Volume: 40
Category: Article
ISSN: 1386-1425
DOI: 10.1016/0584-8539(84)80059-8

No coin nor oath required. For personal study only.

✦ Synopsis

A new 1,4-piperazine-bis-dithiocarbamate sodium salt and its metal complexes have been prepared and characterized by elemental analyses, conductivity measurements, magnetic susceptibilities, thermal analyses (TG and DTG) and spectroscopic (i.r., electronic and EPR) techniques. The ligand is tetrasulphur coordinated to the metals in polymeric structures. The magnetic measurements are indicative of one unpaired electron in the copper(I1) complex; a p value typical of planar low-spin complexes has been obtained in the case of the cobalt(H) derivative,while a distortion from the planarity is suggested in the case of the nickel(I1) complex. Tentative structures of the complexes are proposed on the basis of the obtained results.

📜 SIMILAR VOLUMES

Spectroscopic and thermogravimetric stud

Spectroscopic and thermogravimetric studies of Co(II)-nucleotides complexes

✍ A. Caubet; V. Moreno; A. Labarta; X. Tejada 📂 Article 📅 1990 🏛 Elsevier Science 🌐 English ⚖ 737 KB

Electrometric, spectroscopic and thermog

Electrometric, spectroscopic and thermogravimetric studies on lanthanide-arylhydrazones of benzoylacetone and dibenzoylmethane complexes

✍ Y.M. Issa; H.A. Mohamed 📂 Article 📅 1990 🏛 Elsevier Science 🌐 English ⚖ 597 KB

Crystal Structure and Spectroscopic Stud

Crystal Structure and Spectroscopic Studies of Bis (morpholine dithiocarbamate) Nickel(II) Complex, Ni(C4H8ONCS2)2

✍ Su Pan; Ying Wang 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 270 KB 👁 1 views

Synthetic, spectroscopic and antimicrobi

Synthetic, spectroscopic and antimicrobial studies of bis(dialkyldithiocarbamato)diorganodithiophosphatobismuth(III) complexes

✍ H. P. S. Chauhan; Nagulu Meera Shaik; U. P. Singh 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 132 KB 👁 2 views

Potentiometric, spectrometric, thermogra

Potentiometric, spectrometric, thermogravimetric, conductimetric and magnetic studies of lanthanum complexes with some nitroso naphthols

✍ N.T. Abdel-Ghani; Y.M. Issa; S.A. Abdel-Latif 📂 Article 📅 1989 🏛 Elsevier Science 🌐 English ⚖ 795 KB

Chemistry of iron complexes—II. Spectros

Chemistry of iron complexes—II. Spectroscopic, magnetic and other studies of new complexes of iron(III) with bis(tertiary phosphine/arsine oxides)

✍ T.S. Lobana; H.S. Cheema; S.S. Sandhu 📂 Article 📅 1986 🏛 Elsevier Science 🌐 English ⚖ 272 KB

Spectroscopic (i.r., far i.r., ESR, u.v.-vis) , magnetic, TGA, molar conductance and X-ray diffraction studies of new complexes of iron(III) halides with bis(tertiary phosphine/arsine oxides) Ph2E(O)(CH2),E(O)Phz(L-L ) have been reported. The complexes are of the types: (a) [Fe(L-L)2CI] [FeCI4]2 (n