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Spectroscopic, kinetic and mechanistic studies of the influence of ligand and substrate concentration on the activation by peroxides of CuI–thiolate and other CuI complexes

✍ Scribed by Gilbert, Bruce C.; Silvester, Stephen; Walton, Paul H.


Book ID
118739934
Publisher
Royal Society of Chemistry
Year
1999
Tongue
English
Weight
200 KB
Volume
6
Category
Article
ISSN
1472-779X

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✍ Natalya Hessenauer-Ilicheva; Alicja Franke; Maria Wolak; Tsunehiko Higuchi; Rudi 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 313 KB 👁 2 views

## Abstract Kinetic and mechanistic studies on the formation of an oxoiron(IV) porphyrin cation radical bearing a thiolate group as proximal ligand are reported. The **SR** complex, a functional enzyme mimic of P450, was oxidized in peroxo‐shunt reactions under different experimental conditions wit