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Spectroscopic ionicity and chemical shift of the K-absorption edge in intermetallic compounds

✍ Scribed by K.N. Saxena; N.N. Saxena; R.G. Anikhindi

Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
304 KB
Volume
30
Category
Article
ISSN
0009-2614

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✦ Synopsis

The concept of spectroscopic ionicity of the chemica! bond rnther than that of the effective nucl~r charge may be suitable for the interpietation of obsetied chemical shifts. AII empirics1 relationship, li= rn@ + 6, has been proposed between : .*hespe&roscopicionicityfi and the-chemitil shift ti (eV). This rc:la~on holds good for both the met&ntom and metalloid-atom in binary interme'tallic compounds. . .I. ,htroduction 2. Discussion Recently Sapre and Mande [l] have shown in the '. '_ ,' : OF THE #-ABSORPTION EDGE ti IWTERhfETXLLIC.COhfPOUNDS. : :,

πŸ“œ SIMILAR VOLUMES

Trends in atomic spin-orbit splittings a
Trends in atomic spin-orbit splittings and chemical shifts of the K-absorption edges
✍ K.N. Saxena πŸ“‚ Article πŸ“… 1976 πŸ› Elsevier Science 🌐 English βš– 254 KB

## Proposed new intcrprctaiion in terms of atomic spin-orbit splittings of the constiiuent atoms satisfactorily explains both the nature and the magnitude of chcmicnl shifts of the K-absorption ed:cs.