Spectroscopic investigation of the electronic structure of the chlorine molecule in the VUV
✍ Scribed by Thomas Moeller; Bernhard Jordan; Peter Gürtler; Georg Zimmerer; Dieter Haaks; Jacques Le Calve; Marie-Claude Castex
- Book ID
- 107941923
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 1024 KB
- Volume
- 76
- Category
- Article
- ISSN
- 0301-0104
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Higher excited electronic states of the van der Waals molecule 39 KAr have been investigated using a supersonic beam and a two-step excitation. Four hundred seventy Doppler-free lines have been observed in the second step leading to the electronic states 5d 2 ⌺, 5d 2 ⌸, 5d 2 ⌬, and 7s 2 ⌺. The spect
Evidence is being presented that F2 has a different type of electronic structure than have Cl2. Br2. as 2s. suggested by the quanticule theory. The internuclear distance, the vibrational force constant and ew changes on excitation for F2 do not agree with those expected for the structures Xt Z2 X"