Spectroscopic investigation of systems with a strong hydrogen bond in the gas phase at high temperatures
โ Scribed by I. V. Gerasimov; A. I. Kul'bida; K. G. Tokhadze; V. M. Shraiber
- Publisher
- Springer US
- Year
- 1980
- Tongue
- English
- Weight
- 472 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0021-9037
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Infrared fluorescence and double infrared resonance have been used to measure the V-T relaxation of CD3F and CD 4 in mixtures with He, He, At, Kr, Xe and HCI in the gas phase and in the liquid Ar, Kr, Xe. It is shown that the temperature dependence of V-T probabilities in the interval 350-150ยฐK can
## Abstract The kinetics of gasโphase reaction of CH~3~CF~2~I with HI were studied from 496 to 549K and have been shown to be consistent with the following mechanism: equation image A least squares treatment of the data gave where ฮธ = 2.303 __RT__ kcal/mole. The observed activation energy __E__