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Spectroscopic inversion of the mesomeric effect of the four halogens in ring-substituted acetophenone derivatives

✍ Scribed by R. Thijs; Th. Zeegers-Huyskens


Book ID
108007054
Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
340 KB
Volume
38
Category
Article
ISSN
1386-1425

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Experimental studies of the anomeric eff
✍ Harold Booth; J. Mark Dixon; Khedhair A. Khedhair πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 French βš– 763 KB

A bstracr: The ring inversion equilibrium in carbomethoxycyclohexanne is compared with those in 2-carbomethoxytetrahydropyran and 2-carbomethoxypiperidine through a variable temperature nmr study of the positions of equilibria. The derived A%, values (kcal mol-t) of -1.24 (cyclohexane), -1.69 (tetra