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Spectroscopic Identification of the Active Site for CO Oxidation on Rh/Al2O3 by Concentration Modulation in situ DRIFTS

✍ Scribed by M. Cavers; J.M. Davidson; I.R. Harkness; L.V.C. Rees; G.S. McDougall


Book ID
112255902
Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
68 KB
Volume
188
Category
Article
ISSN
0021-9517

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We have characterized the adsorption of Co(II) on the (0001) and (11 02) surfaces of ␣-Al 2 O 3 single crystals under ambient conditions using polarization-dependent grazing-incidence X-ray absorption fine structure spectroscopy, in combination with bond valence modeling. Co(II) ions were found to b