Spectroscopic effects of a breakdown of the Born-Oppenheimer approximation
✍ Scribed by Strickler, S. J.
- Book ID
- 118245425
- Publisher
- American Chemical Society
- Year
- 1976
- Tongue
- English
- Weight
- 859 KB
- Volume
- 80
- Category
- Article
- ISSN
- 0022-3654
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📜 SIMILAR VOLUMES
Evidence demojhstsating an explicit nuclear coordinate dependence bf efectr&c matrix e&&s in the tran&ion \_ moment for phosphorescence to the ground state'vibration~ maRifofd has been found for substituted benzenes by an opticaliy detected microwave double resonance esperimen:. Theoretical expressi
## Abstract A new derivation of the Born–Oppenheimer separation of electronic and nuclear motion is presented. The arguments used differ from those in earlier works in not being specially designed for molecules. Instead they aim at an intuitive understanding of the qualitative behavior of the low e
By means of a D v and D B formalism for correction parameters, expressions were derived for higher-order Dunham coefficients, Y \* £J 04 , Y \* £J 12 , and Y \* £J 21 , in which contributions of the breakdown of the Born-Oppenheimer approximation were taken into account. Including Y \* £J 04 , Y \*