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Spectroscopic definition of the non-heme iron active site in bleomycin

✍ Scribed by Kelly E. Loeb; Jeffrey M. Zaleski; Tami E. Westre; Richard J. Guajardo; Pradip K. Mascharak; Britt Hedman; Keith O. Hodgson; Edward I. Solomon


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
89 KB
Volume
59
Category
Article
ISSN
0162-0134

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Hemoglobin (Hb) from Chelidonichthys kumu was studied by resonance Raman and electronic absorption spectroscopy in the iron(III) and iron(II) states and in the presence of and CO at various pH values. All forms showed O 2 the appearance of two m(CxC) stretching modes around 1620 and 1630 cm-1 in con