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Spectroscopic Characterization of Reaction Intermediates in a Model for Copper Nitrite Reductase

✍ Scribed by Masato Kujime; Hiroshi Fujii


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
118 KB
Volume
118
Category
Article
ISSN
0044-8249

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The transition state structure for the hydride transfer between 1,4-dihydronicotinamide and the flavin isoalloxazine moiety has been characterized by means of the AM1 and PM3 semiempirical methods. The distance between the initially H-bonded carbon atom of 1,4dihydronicotinamide and the nitrogen ato