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Spectroscopic characterization of lanthanide octaethylporphyrin sandwich complexes. Effects of strong .pi..pi. interaction

✍ Scribed by Duchowski, John K.; Bocian, David F.

Book ID: 126906129
Publisher: American Chemical Society
Year: 1990
Tongue: English
Weight: 925 KB
Volume: 112
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00165a009

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## Abstract The Gd(III) complexes of the two dimeric ligands [en(DO3A)~2~] {__N__,__N__^′^‐bis[1,4,7‐tris(carboxymethyl)‐1,4,7,10‐tetraazacyclododecan‐10‐yl‐methylcarbonyl]‐__N__,__N__^′^‐ethylenediamine} and [pi(DTTA)~2~]^8−^ [bisdiethylenetriaminepentaacetic acid (__trans__‐1,2‐cyclohexanediamine