## Abstract Gas phase emission and laser excitation spectra of the Ã^2^E↔X̃^2^E (Σ = +½, −½) transition of rotationally/vibrationally cooled 1‐chloro‐ and 1‐bromo‐1,3‐pentadiyne cations have been obtained. The emission was excited by electron impact on a seeded helium supersonic free jet and the fl
✦ LIBER ✦
Spectroscopic characterisation of open-shell cations. Laser excitation spectra of XCCX+ (X = Cl, Br)
✍ Scribed by John P. Maier; Liubomir Misev
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 546 KB
- Volume
- 58
- Category
- Article
- ISSN
- 0168-1176
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A new radical cation having the methyl carbene type structure [CH3CHCIH]" has been characterized in the gas phase. It is readily generated by the dissociative ionization [CH3CHClC02H]" + C02+[CH3CHC1H]". Its enthalpy of formation has been estimated to be 951 kJ mol-l, close to that of [CH3CH2CI]". T