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Spectroscopic and structural properties of some molybdenum and tungsten polyoxoperoxo complexes. A comparison with mononuclear complexes

โœ Scribed by Francesco P. Ballistreri; Gaetano A. Tomaselli; Rosa Mariaria Toscano; Valeria Conte; Fulvio Di Furia


Publisher
Elsevier Science
Year
1994
Weight
430 KB
Volume
89
Category
Article
ISSN
0304-5102

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## Abstract Reaction of WX~6~ (X = Cl or Br) with O(SiMe~3~)~2~ in CH~2~Cl~2~, followed by addition of MeCN and a further equivalent of O(SiMe~3~)~2~ in CH~2~Cl~2~ gives [WO~2~X~2~(MeCN)~2~] in situ, which subsequently react with the dithioethers MeS(CH~2~)~2~SMe, __i__PrS(CH~2~)~2~S__i__Pr or 1,4โ€