Spectroscopic and structural properties of copper(I)-thiolate clusters: Model complexes for copper-thioneins?
✍ Scribed by Markus Baumgartner; Erich Dubler
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 68 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0162-0134
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## Abstract Copper(I) bromide complexes (2a and 2b) of NHC–phenolimine ligand precursors {3‐[(1__R__,2__R__)‐2‐{[1‐(3,5‐di‐__tert__‐butyl‐2‐hydroxyphenyl)meth‐(__E__)‐ylidene]amino}cyclohexyl]‐1‐isopropyl‐4‐phenyl‐3__H__‐imidazol‐1‐ium bromide (1a) and 3‐[(1__R__,2__R__)‐2‐{[1‐(2‐hydroxyphenyl)meth
Crystal structure of [Cu(hsm) 2 (sac) 2 ] (hsm is histamine and sac is saccharinate) complex has been determined by X-ray diffraction analyses and its magnetic environment has been identified by electron paramagnetic resonance (EPR) technique. The title complex crystallizes in the monoclinic system,