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Spectroscopic and kinetic evidences for the formation of a 1∶1 mixed complex of MoVand VIVin perchloric medium

✍ Scribed by Daniel O. Mártire; Mario R. Féliz; Alberto L. Capparelli

Publisher
Springer
Year
1994
Tongue
English
Weight
257 KB
Volume
19
Category
Article
ISSN
0340-4285

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✦ Synopsis

The kinetics of interaction of Mo20~ § with VO 2+ was studied in HC104 medium at 25 ~ C and ionic strength of 2 M by the stopped-flow technique. Under conditions of excess VO 2 + a reaction mechanism is proposed to account for the observed pseudo-first order kinetics. For the overall process, 1/2 [MozO4(H20)6] 2 § + VO 2 +~.~-C + H +, the equilibrium constant (K = 33 M 1/2) was determined by absorbance measurements.

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## Abstract Kinetic and thermodynamic investigations were performed for a mixed aqueous‐organic, 1:1 (v/v) water–1,4‐dioxane medium, which was found to be an efficient solvent for the interaction of a neutral dichlorotris(triphenylphosphine) ruthenium(II), RuCl~2~(PPh~3~)~3~ complex with carbon mon