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Spectroscopic and electrochemical properties of the isomeric bidiazine complexes [(C5Me5)CiRh(bdz)]+ and (C5Me5)Rh(bdz) and their relevance to the catalysis of the 2 H+ → H2 reaction by 2,2′-bipyridine analogues

✍ Scribed by Monika Ladwig; Wolfgang Kaim


Book ID
103224396
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
718 KB
Volume
419
Category
Article
ISSN
0022-328X

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✍ Paul-Michael Pellny; Vladimir V. Burlakov; Wolfgang Baumann; Anke Spannenberg; U 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 213 KB 👁 1 views

The reactions of the bis(trimethylsilyl)acetylene permethylmetallocene complexes Cp 2 M(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (1), M = Zr (2)) with H 2 O and CO 2 were studied and compared to those of the corresponding metallocene complexes Cp 2 M(L)(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (3), L = ± ; M = Zr,