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Spectroscopic and Electrochemical Characterization of an Aqua Ligand Exchange and Oxidatively Induced Deprotonation in Diiron Complexes

✍ Scribed by Chardon-Noblat, Sylvie; Horner, Olivier; Chabut, Barbara; Avenier, Frédéric; Debaecker, Noëlle; Jones, Peter; Pécaut, Jacques; Dubois, Lionel; Jeandey, Claudine; Oddou, Jean-Louis; Deronzier, Alain; Latour, Jean-Marc

Book ID
127088629
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
213 KB
Volume
43
Category
Article
ISSN
0020-1669

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## Abstract A dinuclear manganese complex {[Mn~2~^II,III^L(μ‐OAc)~2~]ClO~4~} has been synthesised, where L is the dianion of 2‐{[bis(pyrid‐2‐ylmethyl)amino]methyl}‐6‐{[(3,5‐di‐__tert__‐butyl‐2‐hydroxybenzyl)(pyrid‐2‐ylmethyl)amino]methyl}‐4‐methylphenol, an unsymmetric binucleating ligand with two