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Spectroscopic and Computational Investigations of Stable Radical Anions of Triosmium Benzoheterocycle Clusters

✍ Scribed by Carlo Nervi; Roberto Gobetto; Luciano Milone; Alessandra Viale; Edward Rosenberg; Dalia Rokhsana; Jan Fiedler

Publisher: John Wiley and Sons
Year: 2003
Tongue: English
Weight: 266 KB
Volume: 9
Category: Article
ISSN: 0947-6539
DOI: 10.1002/chem.200305198

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## Abstract The didehydro[n]annulenes **1** (n = 14), **2** (n = 18), and **3** (n = 22) are oxidized to radical cations. Reduction of the title compounds leads to radical anions and, in the case of **2** and **3**, to radical trianions. The hyperfine data of the paramagnetic derivatives are ration