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Spectroscopic and chromatographic investigation of the hydrogen bonds in higher aliphatic acids

✍ Scribed by Józef S̀liwiok; Teresa Kowalska

Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
132 KB
Volume
22
Category
Article
ISSN
0026-265X

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Low-Barrier Hydrogen Bonding in Aqueous
Low-Barrier Hydrogen Bonding in Aqueous and Aprotic Solutions of Dicarboxylic Acids: Spectroscopic Characterization
✍ Constance S. Cassidy; Jing Lin; John B. Tobin; Perry A. Frey 📂 Article 📅 1998 🏛 Elsevier Science 🌐 English ⚖ 143 KB

We present additional spectroscopic evidence for the formation of low-barrier hydrogen bonds (LBHBs) within vicinal and geminal dicarboxylic acid monoanions. Hydrogen ciscyclohexane 1,2-dicarboxylate, displays low-field 1 H NMR signals in aprotic solvents at 19.3 to 19.7 ppm, depending on the solven