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Spectrophotometric Study of Complexation Equilibria Involving a Metal and Coloured and Buffer Ligands by the Competitive Effect of the Two Ligands

✍ Scribed by Ohyoshi, Emiko.

Book ID
124155715
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
330 KB
Volume
57
Category
Article
ISSN
0003-2700

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## Abstract The complexation kinetics of the two macrocycles **1** and **2** with Co^2+^, Ni^2+^, Cu^2+^ and Zn^2+^ have been measured by pH‐stat techniques. The rates are first order in metal and ligand concentration and depend upon the pH. This results from the different reactivities of the vario