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Spectrophotometric studies of tin (II) and tin (IV) dissolved together in pure methanol and in methanol-carbon tetrachloride

✍ Scribed by P.A.D. de Maine; M.M. de Maine

Book ID
118903794
Publisher
Elsevier Science
Year
1959
Weight
288 KB
Volume
11
Category
Article
ISSN
0022-1902

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Addition of methanol decreases AG", AH' and As0 of the exchange of Naf or Cs+ for H+ in tin(W) antimonate. Thus, the increase of selectivity constant is due to the decrease in the enthalpy term. On going from 30 to 90% (w/w) methanol, negative enthalpy and entropy changes occur may be due to chemiso