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Spectrophotometric determination of traces of ruthenium with o-tolidine

✍ Scribed by Raúl S. De Pablo

Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
233 KB
Volume
65
Category
Article
ISSN
0003-2670

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✦ Synopsis

o-Tolidine is known to react with free chlorine, gold(IXI), osmium tetroxide, ruthenium salts, tungstates, etc. la2 but it has not been applied to the determination ofruthenium via its reaction with rhthenium tetroxide. This procedure is less sensitive than the catalytic cerium-arsenic method 3, but is more sensitive than any of the following methods: thiourea, diphenylthiourea, dithiooxamide, diphenylthiosemicarbazide, o-phenanthroline, p-nitrosodimethylaniline3.

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