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Spectrophotometric determination of equilibrium constants of two mutual competitive reactions by the method of isosbestic points

✍ Scribed by Jie Zhou; Siu-Fu Zou; Wei-An Liang


Book ID
118996357
Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
421 KB
Volume
40
Category
Article
ISSN
0039-9140

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Formation constants for binary complexes of cyclohexaamylose (Cy) and p-nitrophenoll p-nitrophenolate (PNP/PNP-) are determined by means of a novel acid-base spectrophotometric analysis. Thermodynamic parameters A Ho and AS0 are derived from the temperature dependences of these constants in the rang