✦ LIBER ✦
Spectrophotometric and Nuclear Magnetic Resonance Study of Temperature- and Pressure-induced Changes in the Intimate Solvation of Neodymium (III) in N, N-Dimethylformamide and Trimethylphosphate
✍ Scribed by Dino L. Pisaniello; Peter J. Nichols; Yves Ducommun; André E. Merhach
- Publisher
- John Wiley and Sons
- Year
- 1982
- Tongue
- German
- Weight
- 162 KB
- Volume
- 65
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
The temperature‐ and pressure‐dependent equilibria for the addition of an extra N, N‐dimethylforrnamide (DMF) or trimethylphosphate (TMP) ligand onto [Nd (DMF)~8~]^3+^‐ and [Nd(TMP)~6~]^3+^‐species respectively have been measured by visible spectrophotometry. Complementary NMR. studies on other lanthanide ions show a gradual shift in preference for the lower coordination number across the lanthanide series.