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Spectrometric determination of gold, platinum and palladium in geological materials by d.c. arc plasma

✍ Scribed by M. Tripković; M. Todorović; I. Holclajtner-Antunović


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
794 KB
Volume
296
Category
Article
ISSN
0003-2670

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✦ Synopsis


A method for the separation and determination of Pt, Au and Pd in various geological materials by coprecipitation with tellurium and applying two spectrometric methods was considered in detail. Particular attention was paid to the influence of matrix elements on the determination of these metals. In one instance the metals were determined in solution by applying a U-shaped arc stabilized by an argon vortex and in the other in the solid sample by applying a vertical arc burning in a stream of a'rgon-oxygen. The accuracy of the method was verified using the international reference standard SARM-7, and the results achieved were compared with published data.


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## AbStM!t An acid decomposition procedure at room temperature for the determination of gold in geological materials is described. Sample decomposition is effected by treatment with hydrochloric acid and bromine for 24 h. From the resulting bromine extract the noble metal is coprecipitated with te